... and fix that option the other commit introduced

Take what I learned from @tomprince in
https://whetstone.privatestorage.io/privatestorage/PrivateStorageio/-/merge_requests/220#note_17605 :
Assigning a service a `startAt' will make timer.target start it,
no need to also have it `wantedBy' multiuser.target.

Also add megacli2prom to the path even if it should be already because
of megacli2prom.  Better be safe than sorry.

Thanks to @tomprince for the suggestion.